Let denote the matrix (Loewner order). Most the following inequalities apply to more general linear operators.
Basic inequalities
As you’d expect, there are matrix versions of the Markov and Chebyshev inequalities. A good overview is given in Appendix C here: https://arxiv.org/pdf/quant-ph/0012127
Markov
For matrix and PSD ,
Of course, this reduces to usual Markov inequality (basic inequalities:Markov’s inequality).
Chebyshev
Markov’s inequality extends to Chebyshev’s inequality in the same way as in the scalar case:
A Chernoff-like inequality
For matrix , symmetric matrix and matrix such that where is the conjugate transpose of , we have
We can prove this easily using Markov’s inequality:
Here we’ve used that the exponential of the zero matrix is the identity. Note also that since the trace is a linear operator, so